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The periodic table of the chemical elements, also called the Mendeleev periodic table, is a tabular display of the known chemical elements. First created by Dmitri Mendeleev, the elements were originally arranged by atomic mass. Then in 1911, Henry Moseley rearranged the table more logically according to atomic number so that many chemical properties followed a regular pattern across the table. Each element is listed by its atomic number and chemical symbol. Mendeleev's and Moseley's development of the periodic table was one of the greatest achievements in modern chemistry. Chemists were able to quantitatively explain the behavior of the elements, and to predict the existence of yet undiscovered ones. There are 116 chemical elements whose discoveries have been confirmed. Ninety-four can be found naturally on Earth, and the rest have been produced in laboratories.

The standard table provides the basic information on the elements. There are also other methods for displaying the chemical elements for more details or different perspectives.

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Groups

A group is a vertical column in the periodic table of the elements. There are 18 groups in the standard periodic table. Elements in a group have similar configurations of their valence shell electrons, which gives them similar properties. They can also be called families.

Group numbers

There are three systems of group numbers; one using Arabic numerals (1, 2, w/. 18), another using Roman numerals (I, II, w/. VIII), and one using a combination of Roman numerals and Latin letters (IA, IIA, IB, w/. VIIIA). The Roman numeral names are the original traditional names of the groups; the Arabic numeral names are a newer naming scheme recommended by the International Union of Pure and Applied Chemistry (IUPAC). The IUPAC scheme was developed to replace both older Roman numeral systems as they confusingly used the same names to mean different things.

Standard periodic table

Group 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
Period
1 1
H

2
He
2 3
Li
4
Be

5
B
6
C
7
N
8
O
9
F
10
Ne
3 11
Na
12
Mg

13
Al
14
Si
15
P
16
S
17
Cl
18
Ar
4 19
K
20
Ca
21
Sc
22
Ti
23
V
24
Cr
25
Mn
26
Fe
27
Co
28
Ni
29
Cu
30
Zn
31
Ga
32
Ge
33
As
34
Se
35
Br
36
Kr
5 37
Rb
38
Sr
39
Y
40
Zr
41
Nb
42
Mo
43
Tc
44
Ru
45
Rh
46
Pd
47
Ag
48
Cd
49
In
50
Sn
51
Sb
52
Te
53
I
54
Xe
6 55
Cs
56
Ba
*
72
Hf
73
Ta
74
W
75
Re
76
Os
77
Ir
78
Pt
79
Au
80
Hg
81
Tl
82
Pb
83
Bi
84
Po
85
At
86
Rn
7 87
Fr
88
Ra
**
104
Rf
105
Db
106
Sg
107
Bh
108
Hs
109
Mt
110
Ds
111
Rg
112
Uub
113
Uut
114
Uuq
115
Uup
116
Uuh
117
Uus
118
Uuo

* Lanthanides 57
La
58
Ce
59
Pr
60
Nd
61
Pm
62
Sm
63
Eu
64
Gd
65
Tb
66
Dy
67
Ho
68
Er
69
Tm
70
Yb
71
Lu
** Actinides 89
Ac
90
Th
91
Pa
92
U
93
Np
94
Pu
95
Am
96
Cm
97
Bk
98
Cf
99
Es
100
Fm
101
Md
102
No
103
Lr
Chemical series of the periodic table
Alkali metals2 Alkaline earth metals2 Lanthanides1,2 Actinides1,2 Transition metals2
Poor metals2 Metalloids Nonmetals Halogens3 Noble gases3

1Actinides and lanthanides are collectively known as "Rare Earth Metals".

2Alkali metals, alkaline earth metals, transition metals, actinides, lanthanides, and poor metals are all collectively known as "Metals".

3Halogens and noble gases are also non-metals.

State at standard temperature and pressure

  • those with atomic number in red are gases
  • those with atomic number in blue are liquids
  • those with atomic number in black are solid

Natural occurrence

  • those with solid borders have isotopes that are older than the Earth (Primordial elements)
  • those with dashed borders naturally arise from decay of other chemical elements and have no isotopes older than the earth
  • those with dotted borders are made artificially (Synthetic elements)
  • those without borders have not been discovered yet

Other methods for displaying the chemical elements

And here is the periodic table for magnetic resonance.

Periodicity of chemical properties

Elements adjacent to one another within a group have similar physical properties, despite their significant differences in mass. Elements adjacent to one another within a period, or energy level, have similar mass but different properties.

For example, very near to nitrogen (N) in the second period of the chart are carbon (C) and oxygen (O). Despite their similarities in mass (only a few atomic mass units), they have extremely different properties, as can be seen by looking at their allotropes: diatomic oxygen is a gas that supports burning, diatomic nitrogen is a gas that does not support burning, while carbon is a solid which can be burned. Diamonds which are a form of crystallized carbon can also burn.

In the group known as the halogens, the element chlorine (Cl) falls between fluorine (F) and bromine (Br). Despite their dramatic differences in mass, their allotropes have very similar properties. They are all highly corrosive. Chlorine and fluorine are gases, while bromine is a very low-boiling liquid. Chlorine and bromine are brightly colored, whereas flourine is not.

Explanation of the structure of the periodic table

The primary determinant of an element's chemical properties is its electron configuration, particularly the valence shell electrons. For instance, all atoms whose four valence electrons are found on the p shell will behave similarly, regardless of which energy level that last p shell is on. The shell in which the atom's outermost electrons reside determines the "block" to which it belongs. The number of valence shell electrons determines which family, or group, the element belongs.

The total number of electron shells an atom has determines the period to which it belongs. Each shell is divided into different subshells, which as atomic number increases are filled in roughly this order:

1s 
2s              2p
3s              3p
4s      3d      4p
5s      4d      5p
6s      5d      6p
7s      6d      7p
      4f
      5f
w/.

Hence the structure of the table. Since the outermost electrons determine chemical properties, those with the same number of valence electrons are grouped togetherw/

Progressing through a group from lightest element to heaviest element, the outer-shell electrons (those most readily accessible for participation in chemical reactions) are all in the same type of orbital, with a similar shape, but with increasingly higher energy and average distance from the nucleus. For instance, the outer-shell (or "valence") electrons of the first group, headed by hydrogen all have one electron in an s orbital. In hydrogen, that s orbital is in the lowest possible energy state of any atom, the first-shell orbital (and represented by hydrogen's position in the first period of the table). In francium, the heaviest element of the group, the outer-shell electron is in the seventh-shell orbital, significantly further out on average from the nucleus than those electrons filling all the shells below it in energy. As another example, both carbon and lead have four electrons in their outer shell orbitals.

Because of the importance of the outermost shell, the different regions of the periodic table are sometimes referred to as periodic table blocks, named according to the sub-shell in which the "last" electron resides, e.g. the s-block, the p-block, the d-block, etc.

History

Main article: History of the periodic table

The original table was created without a knowledge of the inner structure of atoms: if one orders the elements by atomic mass, and then plots certain other properties against atomic mass, one sees an undulation or periodicity to these properties as a function of atomic mass. The first to recognize these regularities was the German chemist Johann Wolfgang Döbereiner who, in 1829, noticed a number of triads of similar elements:

Some triads
Element Molar mass
(g/mol)
Density
(g/cm³)
Quotient
(cm³/mol)
chlorine 35.4527 0.003214 11030
bromine 79.904 3.122 25.6
iodine 126.90447 4.93 25.7
calcium 40.078 1.54 26.0
strontium 87.62 2.64 33.2
barium 137.327 3.594 38.2

This was followed by the English chemist John Newlands, who in 1865 noticed that the elements of similar type recurred at intervals of eight, which he likened to the octaves of music, though his law of octaves was ridiculed by his contemporaries. Finally, in 1869, the German Julius Lothar Meyer and the Russian chemist Dmitri Ivanovich Mendeleev almost simultaneously developed the first periodic table, arranging the elements by mass. However, Mendeleev plotted a few elements out of strict mass sequence in order to make a better match to the properties of their neighbours in the table, corrected mistakes in the values of several atomic masses, and predicted the existence and properties of a few new elements in the empty cells of his table. Mendeleev was later vindicated by the discovery of the electronic structure of the elements in the late 19th and early 20th century.

In the 1940s Glenn T. Seaborg identified the transuranic lathanides and the actinides, which may be placed within the table, or below (as shown above).

Further resources

  • 1 Scerri, E.R., references to several scholarly articles by this author.
  • Mazurs, E.G., "Graphical Representations of the Periodic System During One Hundred Years". University of Alabama Press, Alabama. 1974.
  • Bouma, J., "An Application-Oriented Periodic Table of the Elements". J. Chem. Ed., 66 741 (1989).

See also

External links

Periodic table (professional ion)". WebElements.
  • The IUPAC periodic table
  • "Presentation forms of the periodic table". Western Oregon University.
  • "A Brief History of the Development of Periodic Table". Western Oregon University.
  • "Visual Periodic Table". ChemSoc.org.
  • Derived from Chemsoc, with links to other tables under each individual element.
  • Barbalace, Kenneth L., "Biochemical Periodic Tables". KLBProductions.com.
  • Barthelmy, David, "Periodic table" Mineralogy Database. (mineral emphasis)
  • Counterman, Craig, "Periodic Table of the Elements : For each of many properties a separate periodic table and a graph showing the relation with the atomic number". MIT Course 3.091.
  • Gray, Theodore, "Wooden Periodic Table Table" (with samples)
  • Holler, F. James, and John P. Selegue, "Periodic Table of Comic Books". Department of Chemistry, University of Kentucky. 1996-2002.
  • Heilman, Chris, "The Pictorial Periodic Table". (Includes alternate styles: Stowe, Benfey, Zmaczynski, Giguere, Tarantola, Filling, Mendeleev)
  • "Periodic table". Los Alamos National Laboratory's Chemistry Division.
  • "Periodic Table of the Fermi Surfaces of Elemental Solids". The Fermi Surface Database
  • "Interactive NMR Frequency Map". Texas A&M.
  • "Periodic Table Elements". Israel Science and Technology Directory. 1999-2004. (sorted by physical characteristics)
  • "Periodic table applet". Dartmouth College. (Java)
  • Eric Scerri many scholarly articles on the Periodic System by the philosopher-chemist who teaches in the chemistry department at UCLA.
  • "ScienceIsGolden" educational vehicles: a teacher in California has been driving around in vehicles signed by physicists & promoting an educational-form of the periodic table.
  • Periodensystem.com: periodic table with several transations, easy to use
  • Dayah, Michael, "Periodic Table". Large full-color scalable text-only rendering.

  • Periodic tables

    Standard table | Vertical table | Table with names | Names and atomic masses (large) | Names and atomic masses (small) | Names and atomic masses (text only) | Inline F-block | Elements to 218 | Electron configurations | Metals and non metals | Table by blocks
    Lists of Elements
    Name | Atomic symbol | Atomic number | Boiling point | Melting point | Density | Atomic mass
    Groups: 1 - 2 - 3 - 4 - 5 - 6 - 7 - 8 - 9 - 10 - 11 - 12 - 13 - 14 - 15 - 16 - 17 - 18
    Periods: 1 - 2 - 3 - 4 - 5 - 6 - 7 - 8 - 9
    Series: Alkalis - Alkaline earths - Lanthanides - Actinides - Transition metals - Poor metals - Metalloids - Nonmetals - Halogens - Noble gases
    Blocks: s-block - p-block - d-block - f-block - g-block


    Chemistry
    Analytical chemistry | Organic chemistry | Inorganic chemistry | Physical chemistry | Polymer chemistry | Biochemistry | Materials science | Environmental chemistry | Medicinal chemistry | Pharmacy | Thermochemistry | Electrochemistry | Nuclear chemistry | Computational chemistry | Photochemistry
    Periodic table | List of inorganic compounds | List of organic compounds | List of biomolecules

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